EFFECT OF ELECTRON BEAM TREATMENT ON THE STRUCTURE AND PROPERTIES OF PLASMA COATING OF HIGH-SPEED MOLYBDENUM STEEL
https://doi.org/10.57070/10.57070/2304-4497-2025-3(53)-9-13
Abstract
The structure and properties of the surface of a plasma-deposited layer in a nitrogen environment of high-speed molybdenum steel on a substrate of medium-carbon steel grade 30KhGSA were studied using modern physical materials science methods. The deposited layer was irradiated with pulsed electron beams with the following parameters: energy density of 30 J/cm2, duration of one exposure of 50 μs, frequency of 0.3 Hz, number of pulses of 10. In the initial state, the surface layers contain a polycrystalline structure of the dendritic type with a non-uniform distribution of molybdenum, chromium, aluminum, nitrogen and oxygen, surrounded by a developed network of ledeburite eutectic. The relative content of elements (except for Mn, C and O2) decreases as it approaches the substrate. The microhardness of the deposited layer is 5.6 MPa, which increases to 6.2 MPa after a single high-temperature tempering, and to 7.2 MPa after a double tempering. Electron-beam pulsed action performed after a double high-temperature tempering modifies the structure and properties. A quasi-homogeneous distribution of alloying elements, the formation of a fine-grained structure with a grain size of 4 ‒ 6 μm, in the volume of which lamellar martensite was found, were revealed. The previously formed structure of dendritic crystallization is not observed. The microhardness of the deposited layer after electron-beam treatment increases and reaches 8.7 MPa, which is almost 2 times higher than the microhardness of the substrate. The revealed patterns of change in nanohardness and Young's modulus from the distance to the irradiation surface confirm the developed ideas about the nature of hardening of the plasma deposited layer of high-speed molybdenum steel.
About the Authors
Irina V. BaklushinaRussian Federation
Senior Lecturer, Deputy Director of the Institute of Open Education
Anastasia N. Gostevskaya
Researcher, Laboratory of EMIOI, Lecturer
Viktor E. Gromov
Dr. Sci. (Phys.-Math.), Prof., Head of the Chair of Science named after V.M. Finkel’
Yuri F. Ivanov
Dr. Sci. (Phys.-Math.), Chief Researcher
Aleksandr S. Chapaykin
Postgraduate Student
References
1. Kremnev L.S., Onegina A.K., Vinogradova L.A. Features of transformations, structures and properties of molybdenum high-speed steels. Metallovedenie i termicheskaya obrabotka metallov. 2009;12(654):13‒19. (In Russ.).
2. Kremnev L.S. The theory of alloying and the creation of heat-resistant tool steels and alloys based on it. MiTOM. 2008;11:18‒28. (In Russ.).
3. Chaus A.S., Pokorný P., Čaplovič Ľ., Sitkevich M.V., Peterka J. Complex fine-scale diffusion coating formed at low temperature on high-speed steel substrate. Appl. Surf. Sci. 2018;437:257–270.
4. Gerth J., Wiklund U. The influence of metallic interlayers on the adhesion of PVD TiN coatings on high-speed steel. Wear. 2008;264:885–892.
5. Kupalova I.K. Phase analysis and phase composition of high-speed steels (review). Zavodskaya laboratoriya. 1983;1:27‒40. (In Russ.).
6. Emelyushin A.N., Petrochenko E.V., Nefed′ev S.P. Inverstigation of the structure and impact-abrasive resistance of coatings of the Fe-C-Cr-Mn-Si system, additionally alloyed with nitrogen. Welding International. 2013;27(2):150‒153.
7. Nefed'ev S.P., Emelyushin A.N. The effect of nitrogen on the formation of the structure and properties of plasma coatings of type 10P6M5. Vestnik Yugorskogo gosudarstvennogo universiteta. 2021;3(62):33‒45. (In Russ.).
8. Emelyushin A.N., Petrochenko E.V., Nefed'ev S.P. Investigation of the structure and impact-abrasive wear resistance of Fe ‒ C ‒ Cr ‒ Mn ‒ Si system coatings additionally doped with nitrogen. Svarochnoe proizvodstvo. 2011;10:18‒22. (In Russ.).
9. Nefed'ev S.P., Emelyushin A.N. Plasma sur-face hardening. Staryi Oskol: TNT, 2021:156. (In Russ.).
10. Mozgovoi I.V., Shneider E.A. Welding of high-speed steel. Omsk: Izd-vo «OmGTU», 2016:200. (In Russ.).
11. Ivanov Yu.F., Gromov V.E., Potekaev A.I., Guseva T.P., Chapaikin A.S., Vashchuk E.S., Romanov D.A. Structure and properties of R18U surfacing of high-speed steel after its high tempering. Russian Physics Journal. 2023;66(7);731‒739. https://doi.org/10.1007/s11182-023-02999-w
12. Rakhadilov B.K., Zhurerova L.G., Scheffler M., Khassenov A.K. Change in high temperature wear resistance of high speed steel by plasma nitriding. Bulletin of the Karaganda University. Physics Series. 2018;3(91):59–65. EDN: KJWHYN.
13. Aleksandrovich B.L., Geller Yu.A., Kremnev L.S. New high-hardness high-speed steels. Metal Science and Heat Treatment. 1968;1:2‒7.
14. Barchukov D.A., Tsygvintsev A.V., Afanas'eva L.E. Features of the formation of the structure and properties of high-speed steel during pulsed arc welding. Vestnik Tverskogo gosu-darstvennogo universiteta. 2019;4(4):16‒22. (In Russ.).
15. Barchukov D.A., Ilyashenko S.E., Lavrent’ev A.Yu., Zubkov N.S. Improvement of the structural state of high-speed steel to enhance hardening efficiency during heat treatment. Metal Science and Heat Treatment. 2013;17:6‒9.
16. Ivanov Yu.F. Structural and phase transfor-mations in a number of steels under static and dynamic modes of heat treatment: abstract. dissertations, Ph.D. Moscow, 2002:41. (In Russ.).
17. Mishigdorzhiyn U., Semenov A., Ulakhanov N. et al. Microstructure and Wear Resistance of Hot-Work Tool Steels after Electron Beam Surface Alloying with B4 C and Al. Lubricants. 2022;10(5).
18. https://doi.org/10.3390/lubricants10050090; EDN: XTTOFB.
19. Chen X., Konovalov S., Gromov V., Ivanov Yu. Modifying of Structure-Phase States and Properties of Metals by Concentrated Energy Flows. In: Surface Processing of Light Alloys Subject to Concentrated Energy Flows. 2021:1‒52.
20. Rotshtein V.P., Proskurovsky D.I., Ozur G., Ivanov Yu., Markov A. Surface modification and alloying of metallic materials with low-energy high-current electron beams. Surface and Coatings Technology. 2004;180:377‒381. https://doi.org/10.1016/j.surfcoat.2003.10.085
21. Khaidarova A.A., Silantiev S.A. Laser Treat-ment on the Coating Surface Having Been Performed by Means of Plasma Surfacing With Powder Made of M2 Steel. In: IOP Conference Series: Materials Science and Engineering: electronic edition. Yurga: IOP Publishing Ltd, 2016:12062. https://doi.org/10.1088/1757-899X/142/1/012062
22. Samotugin S.S., Butsukin V.V. Increasing of the Service Life of Massive Tools Using Combined Restoration and Hardening Technologies. Russian Engineering Research. 2024;44(8):1154‒1160. https://doi.org/10.3103/S1068798X24701934
Review
For citations:
Baklushina I., Gostevskaya A., Gromov V., Ivanov Yu., Chapaykin A. EFFECT OF ELECTRON BEAM TREATMENT ON THE STRUCTURE AND PROPERTIES OF PLASMA COATING OF HIGH-SPEED MOLYBDENUM STEEL. Bulletin of the Siberian State Industrial University. 2025;(3):3-16. (In Russ.) https://doi.org/10.57070/10.57070/2304-4497-2025-3(53)-9-13