Preview

Bulletin of the Siberian State Industrial University

Advanced search

INFLUENCE OF HYDROGEN ABSORPTION ON DESTRUCTION AND MECHANICAL CHARACTERISTICS OF TITANIUM ALLOY

https://doi.org/10.57070/2304-4497-2024-4(50)-63-71

Abstract

The effect of hydrogen absorption on the nature of destruction and mechanical characteristics of Ti ‒ 6Al ‒ 4V titanium alloy during operation in a hydrogen-containing medium at normal temperatures has been studied. The main mechanism of the hydrogen embrittlement process for (α + β) titanium alloys is described, which consists in the separation and subsequent decomposition of brittle hydride phases. In the course of the study, it was established that during the operation of samples from the alloy under the given composition and parameters of the operating environment there is a saturation of the metal with hydrogen, as evidenced by the increase in its content in the material after operation in comparison with the sample in the initial state. The mechanism of destruction of a metal sample saturated with hydrogen during operation in a hydrogen-containing medium is shown. The fracture surface morphology of the investigated specimen is characteristic of brittle fracture type. Large crater-shaped defects, signs of erosion and cracking are present on the surface of the sample near the fracture zone. The fracture structure is characterized by the presence of “saw teeth”, an extensive system of secondary micro-cracks and their interaction with the main crack is observed, which is a characteristic manifestation of hydrogen embrittlement of a titanium alloy. Near the fracture surface of the sample, degradation of the microstructure is observed, manifested in the formation of micro voids at the interface of the α/β phases initiating destruction. An increase in the microhardness of the metal of the part of the destroyed sample that was in direct contact with the working medium was found to be 35-38%, which may be due to the distribution of finely dispersed titanium hydrides in the region under consideration, which were formed as a result of hydrogen absorption of metal.

About the Authors

Mariya O. Kudryashova
Samara National Research University, «Research and Production Centre «Samara» LLC
Russian Federation

Junior Researcher, postgraduate student of the Department of Metal Technology and Aviation 
Materials Science



Sergei S. Petrov
Samara National Research University, «Research and Production Centre «Samara» LLC

Cand. Sci. (Phys.-Math.), Head of Analytical Department, Associate Professor of the Department of Solid State Physics and Nonequilibrium Systems



Pavel E. Yudin
Samara State Technical University, «Research and Production Centre «Samara» LLC

Cand. Sci. (Eng.), Associate Professor, Director of Science, Associate Professor of the Department «Metal science, powder metallurgy, nanomaterials»



Aleksandr Yu. Ezhov
«KROHNEAutomatics» LLC

Chief Designer



Ol'ga S. Bondareva
Samara National Research University

Cand. Sci. (Eng.), Associate Professor, Associate Professor of the Department of Metal Technology and Aviation Materials Science



Aleksei A. Mel'nikov
Samara National Research University

Cand. Sci. (Eng.), Associate Professor, Associate Professor of the Department of Metal Technology and Aviation Materials Science



References

1. Tal-Gutelmacher E., Eliezer D. Embrit-tlement of Secondary Hydrogen-Containing Phases in Titanium-Based Alloys. In: Glass Physics and Chemistry. Proceedings of the Third Russian-Israeli Bi-National Workshop 2004 «The Optimization of the Composition, Structure, and Properties Of Metals, Oxides, Composites, Nanomaterials, and Amorphous Materials» (St. Petersburg, Russia, June 13–23, 2004). St. Petersburg. 2005;31(1):96–101.

2. https://doi.org/10.1007/s10720-005-0029-5

3. Belova S.B., Kolachev B.A., Mamonov I.M. Diffusion parameters of substitution elements in α- and β-titanium. Nauchnye trudy (Vestnik MATI). 2002;5(77):5–9. (In Russ.).

4. Il'in A.A. The mechanism and kinetics of phase and structural transformations in titanium alloys. Moscow: Nauka. 1994:304. (In Russ.).

5. Il'in A.A., Kolachev B.A., Nosov V.K., Ma-monov A.M. Hydrogen technology of titanium alloys. Moscow: MISIS. 2002:390. (In Russ.).

6. Eliezer D., Tal-Gutelmacher E., Cross C. E., Boellinghaus T. Hydrogen trapping in β-21S titanium alloy. Materials Science and Engineering: A. 2006;421(1–2):200–207.

7. https://doi.org/10.1016/j.msea.2006.01.067

8. Chattoraj I. Stress corrosion cracking (SCC) and hydrogen-assisted cracking in titanium alloys. Stress Corrosion Cracking. 2011:381–408. https://doi.org/10.1533/9780857093769.3.381

9. Gerland M., Lefranc P., Doquet V., Sar-razin-Baudoux C. Deformation and damage mechanisms in an α/β 6242 Ti alloy in fatigue, dwell-fatigue and creep at room temperature. Influence of internal hydrogen. Materials Science and Engineering A. 2009;507(1–2):132–143. https://doi.org/10.1016/j.msea.2008.11.045

10. Conforto E., Guillot I., Feaugas X. Solute hydrogen and hydride phase implications on the plasticity of zirconium and titanium alloys: a review and some recent advances. Philosophical Transactions A. 2017;375(2098):20160417. http://doi.org/10.1098/rsta.2016.0417

11. Barkia B. Viscoplasticité à l’ambiante du titane en relation avec ses teneurs en oxygène et hydrogène. Extended abstract of Doctor’s thesis. 2014:269.

12. http://doi.org/ 10.13140/RG.2.1.1731.8007

13. Wasz M.L., Brotzen F.R., McLellan R.B., Griffin A.J. Effect of oxygen and hydrogen on mechanical properties of commercial purity titanium. International Materials Reviews. 2013:41(1):1–12. https://doi.org/10.1179/imr.1996.41.1.1

14. Tal-Gutelmacher E., Eliezer D. Hydrogen cracking in titanium-based alloys . Journal of Alloys and Compounds. 2005;404-406:621–625. https://doi.org/10.1016/j.jallcom.2005.02.098

15. Nelson H.G. Effect of High Temperature Hydrogen on Titanium Base Alloys. A Publication of The Minerals, Metals & Materials Society. 1996:699.

16. Feaugas X., Conforto E. Influence de l’hydrogène sur les mécanismes de défor-mation et d’endommagement des alliages de titane et de zirconium. PlastOx. 2009:161–178. https://doi.org/10.1051/ptox/2009012

17. Bignon Q., Martin F., Auzoux Q., Wouters Y. Hydrogen impact on the mechanical properties of three titanium alloys. In: 3rd International conference on metals and hydrogen. Gand, Belgium. 2018:11.

18. Malkov I.L., Boitsov I.E., Dmitrienko A.N., Kazimov M.V., Klevtsov V.G., Tumanova N.Yu., Yukhimchuk A.A. Investigation of the hydrogen strength of titanium alloys. Trudy RFYaTs-VNIIEF. 2020;25–2:170–179.

19. EDN:IVVRPB; (In Russ.).

20. https://doi.org/10.53403/9785951504944_2020_25.2_170_179

21. Pittinato G.F., Hanna W.D. Hydrogen in β transformed Ti-6Al-4V. Metallurgical and Materials Transactions B. 1972; 3(11):2905–2909.

22. Hardie D., Ouyang S. Effect of hydrogen and strain rate upon the ductility of mill-annealed Ti6Al4V. Corrosion Science. 1999;41(1):155–177.

23. https://doi.org/10.1016/S0010-938X(98)00109-7

24. Tal-Gutelmacher E., Eliezer D. Hydrogen-assisted degradation of titanium based alloys. Materials Transactions. 2004;45(5):1594–1600. https://doi.org/ 10.2320/matertrans.45.1594

25. Briant C.L., Wang Z.F., Chollocoop N. Hydrogen embrittlement of commercial purity titanium. Corrosion Science. 2002;44(8):1875–1888. https://doi.org/10.1016/S0010-938X(01)00159-7

26. Molokanova A.A., Saulin D.V. Investigation of the processes of hydrogenation of corrosion-resistant alloys and non-ferrous metal alloys. Vestnik PNIPU. 2023;4:92–107. (In Russ.). https://doi.org/10.15593/2224-9400/2023.4.07

27. Chernov I.P., Lider A.M., Cherdantsev Yu.P., Garanin G.V., Nikitenkov N.N., Krening M., Surkov A.S. Defects in titanium initiated by hydrogen. Fizicheskaya mezomekhanika. 2000;3(6):97–103. EDN: KWPJCB. (In Russ.).

28. Vinokur B.I., Belov S.P., Brun M.Ya. Titanium alloys. Metallology of titanium and its alloys. Moscow: Metallurgiya.1992:352. (In Russ.).


Review

For citations:


Kudryashova M., Petrov S., Yudin P., Ezhov A., Bondareva O., Mel'nikov A. INFLUENCE OF HYDROGEN ABSORPTION ON DESTRUCTION AND MECHANICAL CHARACTERISTICS OF TITANIUM ALLOY. Bulletin of the Siberian State Industrial University. 2024;(4):63-71. (In Russ.) https://doi.org/10.57070/2304-4497-2024-4(50)-63-71

Views: 62


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 2304 - 4497 (Print)
ISSN 2307-1710 (Online)