INFLUENCE OF PULSED ION-BEAM TREATMENT ON THE STRUCTURE AND PROPERTIES OF THE ALLOY FORMED BY ELECTRON-BEAM PRINTING WITH VT6SV WIRE
https://doi.org/10.57070/2304-4497-2025-2(52)-27-36
Abstract
A study of the microstructure and properties of a titanium alloy formed during electron beam printing with VT6cw wire after treatment with a pulsed ion beam has been carried out. The samples were obtained at a laboratory facility for electron beam additive manufacturing developed at IFPM SB RAS. The process of forming the samples was carried out by fusing titanium welding wire of the VT6sv brand with a diameter of 1.6 mm under vacuum conditions at a pressure of 10‒3 ‒ 10‒2 Pa. The energy effect using pulsed ion treatment was carried out on a TEMP-4M accelerator at an accelerating voltage of 200 kV, a pulse duration at half the maximum of 100 ns and an energy density of 2 J/cm2. Transmission electron microscopy, atomic force microscopy, and microhardness measurements have shown that exposure to a pulsed ion beam leads to significant changes in the microstructure of the surface: the transformation of the β-phase into the α-phase is observed, as well as the formation of nanoparticles of the Al₃v intermetallic compound. The thickness of the modified layer is about 5.5 microns. A slight increase in microhardness was revealed (from 254.39 to 261.37 HV), while a more uniform distribution of hardness values was achieved. Ion beam treatment can help improve the biocompatibility of titanium implants by eliminating sharp edges that occur during machining and reducing roughness. In comparison with traditional methods of thermal treatment, ion treatment demonstrates a high degree of controllability and adaptability, which makes it promising for use in biomedical systems. The results obtained open up new possibilities for the functionalization of the surface of titanium alloys and have high application potential.
About the Authors
Zeli HanRussian Federation
postgraduate student, engineer
Zhengyuan Li
Dr. Sci. (Eng.), Associate Professor
Vladislav A. Tarbokov
Cand. Sci. (Eng.), Leading Engi
Yurii F. Ivanov
Dr. Sci. (Phys. and Math.), Leading Researcher
Konstantin V. Ivanov
Dr. Sci. (Phys. and Math.), Leading Researcher
Vasilii A. Klimenov
Dr. Sci. (Eng.), Professor
References
1. Gaspar B. Microstructural characterization of Ti – 6Al – 4V and its relationship to sample geometry. Materials Engineering. 2012:22.
2. Ho W.F., Ju C.P., Chern J.H. Structure and properties of cast binary Ti – Mo alloys. Bio-materials. 1999; 20(22):2115–2122.
3. https://doi.org/10.1016/s0142-9612(99)00114-3
4. Suwas S., Vikram R.J. Texture Evolution in Metallic Materials During Additive Manufac-turing. Transactions of the Indian National Academy of Engineering. 2021;6:991–1003.
5. Umansky Ya.S. ed. Introduction to the Physics of Metal Crystallization. Moscow: Izd-vo Mir. 1967:170. (In Russ.).
6. Klimenov V., Kolubaev E., Chumaevskii A., Ustinov A., Strelkova I., Rubtsov V., Gurianov D., Han Z., Ni-konov S., Batranin A., Khimich M. Influence of the Coarse Grain Structure of a Titanium Alloy Ti – 4Al – 3V Formed by Wire-Feed Electron Beam Additive Manufacturing on Strain Inhomogeneities and Frac-ture. Materials. 2023;16(11):3901.
7. https://doi.org/10.3390/ma16113901
8. Klimenov V.A., Kolubaev E.A., Han Z. Chu-maevskii A.V., Klopotov A.A., Ustinov A.M., Kovalevskaya Z.G., Moskvichev E. Pan M. In-fluence of anisotropy properties and structural inhomogeneity on elasticity and fracture of ti-tanium alloys produced by electron-beam melt-ing. The International Journal of Advanced Manufacturing Technology. 2024; 135:5575–5594.
9. Osipovich K., Kalashnikov K., Chumaevskii A., Gurianov D., Kalashnikova T., Vorontsov A., Zykova A., Utyaganova V., Panfilov A., Niko-laeva A., Dobrovolskii A., Rubtsov V., Kolubaev E. Wire-Feed Electron Beam Additive Manu-facturing: A Review. Metals. 2023;13(2):279.
10. https://doi.org/10.3390/met13020279
11. Zhang T., Liu C.T. Design of titanium alloys by additive manufacturing: A critical review. Ad-vanced Powder Materials. 2021;1(1):1–11. https://doi.org/10.1016/j.apmate.2021.11.001
12. Chumaevskii A., Tarasov S., Gurianov D., Moskvichev E., Rubtsov V., Savchenko N., Panfilov A., Korsunsky A., Kolubaev E. Analysis of the Structure and Properties of As-Built and Heat-Treated Wire-Feed Electron Beam Additively Manufactured (WEBAM) Ti – 4Al – 3V Spher-ical Pressure Vessel. Metals. 2024;14(12):1379. https://doi.org/10.3390/met14121379
13. Tekdir H., Yetim A.F. Additive manufactur-ing of multiple layered materials (Ti6Al4V/316L) and improving their tribolog-ical properties with glow discharge surface modification. Vacuum. 2021;184:109893.
14. Vanmeensel K., Lietaert K., Vrancken B., Dadbakhsh S., Li X., Kruth J.P., Krakhmalev P., Yadroitsev I., Humbeeck J.V. 8-Additively manufactured metals for medical applications. Additive manufacturing Materials, Processes, Quantifications and Applications. 2018:261–309.
15. Lu Y., Turner R., Brooks J., Basoalto H. Mi-crostructural characteristics and computation-al investigation on electron beam welded Ti – 6Al – 4V alloy. Journal of Materials Pro-cessing Technology. 2021;288:116837.
16. https://doi.org/10.1016/j.jmatprotec.2020.116837
17. Popovich A.A., Sufiiarov V.S., Borisov E.V., Polozov I.A., Masaylo D.V. Grigoriev A.V. An-isotropy of mechanical properties of products manufactured using selective laser melting of powdered materials. Russian Journal of Non-Ferrous Metals. 2017;58:389–395.
18. Xie B., Gao K. Research progress of surface treatment technologies on titanium alloys: a mini review. Coatings. 2023;13(9):1486.
19. https://doi.org/10.3390/coatings13091486
20. Wang M., Li H.Q., Guo H., Feng L., Liu Sh.-Y., Fang X.-Y. Evolution of microstructure and intervariant boundaries of α phase in electron beam melted and heat-treated Ti – 6Al – 4V al-loy. Rare Metals. 2021;40:2118–2126.
21. Slobodyan M., Pesterev E., Markov A. A re-view of high-energy processing techniques ap-plied for additive manufacturing and surface engineering of cemented carbides and cermets. Journal of Manufacturing Processes. 2023;105(2):124–186. https://doi.org/10.1016/j.jmapro.2023.09.030
22. Guehennec L.L., Soueidan A., Layrolle P., Amouriq Y. Surface treatments of titanium den-tal implants for rapid osseointegration. Dental Materials. 2007;23(7):844–854.
23. https://doi.org/10.1016/j.dental.2006.06.025
24. Panin A., Kazachenok M., Perevalova O., Martynov S., Panina A., Sklyarova E. Continuous Electron Beam Post-Treatment of EBF3-Fabricated Ti – 6Al – 4V Parts. Metals. 2019;9(6):699.
25. https://doi.org/10.3390/met9060699
26. Remnev G.E., Isakov I.F., Opekounov M.S., Matvienko V.M., Ryzhkov V.A., Struts V.K., Grushin I.I., Zakoutayev A.N., Potyomkin A.V., Tarbokov V.A., Pushkaryov A.N., Kutu-zov V.L, Ovsyannikov Yu.M. High intensity pulsed ion beam sources and their industrial applica-tions. Surface and Coatings Technology. 1999;114(2-3):206–212. https://doi.org/10.1016/S0257-8972(99)00058-4
27. Klimenov V., Kolubaev E., Chumaevskii A., Tarbokov V., Han Z. Prospective Surface Treatment Technologies for Ti Alloys Ob-tained by Additive Manufacturing. Abstracts at 9th International Congress on Energy Fluxes and Radiation Effects (EFRE-2024). Tomsk, 2024:296 – 296.
28. Tarbokov V.A., Pavlov S.K., Remnev G.E., Nochov-naya N.A., Eshkulov U.É. Titanium Alloy Surface Complex Modification. Metallurgist. 2019; 62:1187–1193.
29. https://doi.org/10.1007/s11015-019-00772-4
30. Krivonosova E.A., Akulova S.N., Myshkina A.V. Study of the influence of different types of heat treatment on the physical and mechani-cal properties of titanium alloy. Khimiya. Ekologiya. Urbanistika. 2021;1:354–358. (In Russ.).
Review
For citations:
Han Z., Li Zh., Tarbokov V., Ivanov Yu., Ivanov K., Klimenov V. INFLUENCE OF PULSED ION-BEAM TREATMENT ON THE STRUCTURE AND PROPERTIES OF THE ALLOY FORMED BY ELECTRON-BEAM PRINTING WITH VT6SV WIRE. Bulletin of the Siberian State Industrial University. 2025;(2):27-36. (In Russ.) https://doi.org/10.57070/2304-4497-2025-2(52)-27-36